Scientific American Supplement, No. 415, December 15, 1883 by Various
page 71 of 126 (56%)
page 71 of 126 (56%)
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to those unfamiliar with recent researches in this field.
It is well known that in coal-tar is found a series of ammonia-like bases, aniline or amido-benzol, toluidine or amido-toluol, and xylidine or amido-xylol, which are utilized practically in the manufacture of the so-called aniline dye-colors. It is perhaps not so well known that there are other series of bases found there too. The first of these is the pyridine series, including _pyridine_, C_{5}H_{5}N, _picoline_ (methyl-pyridine), C_{5}H_{4}N(CH_{3}), _lutidine_ (dimethyl-pyridine), C_{5}H_{5}N(CH_{3})_{2}, and _collidine_ (trimethyl-pyridine), C_{5}H_{2}N(CH_{3})_{3}. This series is also found in relatively larger proportion in what is known as Dippel's oil, the product of the dry distillation of bones. The second series is the quinoline series, including _quinoline_, C_{9}H_{7}N, _lepidine_ (methyl-quinoline), C_{10}H_{9}N, and _cryptidine_ (dimethyl-quinoline), C_{11}H_{11}N. The two compounds which give name to these series, pyridine, C_{5}H_{5}N, and quinoline, C_{9}H_{7}N, respectively, bear to each other a relation analogous to that existing between benzol, C_{6}H_{6}, and naphthalene, C_{10}H_{8}; and the theory generally accepted by those chemists who have been occupying themselves with these bases and their derivatives is that pyridine is simply benzol, in which an atom of nitrogen replaces the triad group, CH, and quinoline, the naphthalene molecule with a similar change. Indeed, Ladenberg has recently succeeded in obtaining benzol as an alteration product from pyridine, in certain reactions. Moreover, from methyl-pyridine, C_{5}H_{4}N(CH_{3}), would be derived an acid know as pyridine-carboxylic acid, C_{5}H_{4}N(COOH), just as benzoic acid, C_{6}H_{5}COOH, is derived from methyl-benzol, C_{6}H_{5}CH_{3}, and from dimethyl-pyridine, C_{5}H_{3}N(CH_{3})_{2}, an acid known as |
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