Scientific American Supplement, No. 415, December 15, 1883 by Various
page 75 of 126 (59%)
page 75 of 126 (59%)
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acid, which is a quinoline-carboxylic acid, C_{9}H_{6}N(COOH),
cinchomeronic acid, which has just been stated to be a pyridine dicarboxylic acid, and a pyridine tricarboxylic acid. When cinchonine is treated with potassium hydrate, it is decomposed into quinoline and a solid body, which on further treatment yields a liquid base, C_{7}H_{9}N, which is probably lutidine. It has been found, moreover, that both tetrahydroquinoline and dihydroquinoline, hydrogen addition products of quinoline, are present. When cinchonine is distilled with solid potassium hydrate, it yields pyrrol and bases of both the pyridine and quinoline series. _Cinchonidine_, when heated with potassium hydrate, yields quinoline also, and with nitric acid the same products as cinchonine. _Strychnine_ has been found to be a tertiary amine. When distilled with potassium hydrate, quinoline is formed. _Brucine_ is a tertiary diamine, that is, formed by substitution in a double ammonia molecule. When distilled with potassium hydrate it yields quinoline, lutidine, and two isomeric collidines. The alkaloid _atropine_ has been quite thoroughly studied with results of great interest. When heated with baryta-water or hydrochloric acid, it takes up a molecule of water and is split into tropine, C_{8}H_{15}NO, and tropic acid, C_{9}H_{10}O_{3}. This latter is phenyl-oxypropionic acid. Tropine, when heated to 180°C. with concentrated hydrochloric acid, splits off a molecule of water, and yields tropidine, C_{8}H_{13}N, a liquid base, with an odor resembling conine. When this tropidine is heated with an excess of bromine, it yields dibrompyridine. |
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