Scientific American Supplement, No. 458, October 11, 1884 by Various
page 23 of 144 (15%)
page 23 of 144 (15%)
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If dried starch grains are rubbed between two glass plates, the grains
will be seen under the microscope to be fissured, and if then wetted and filtered, the filtrate will be a perfectly clear liquid showing a strong starch reaction with iodine. Since no solution is obtained from uninjured grains, even after soaking for weeks in water, Brukner concludes that the outer layers of the starch grains form a membrane protecting the interior soluble layers from the action of the water. The soluble filtrate from starch paste also contains a substance identical with granulose. Between the two kinds of starch, the granular and that contained in paste, there is no chemical but only a physical difference, depending on the condition of aggregation of their micellæ. W. Nageli maintains that granulose, or soluble starch, differs from amylodextrin in the former being precipitated by tannic acid and acetate of lead, while the latter is not. Brukner fails to confirm this difference, obtaining a voluminous precipitate with tannic acid and acetate of lead in the case of both substances. Another difference maintained by Nageli, that freshly precipitated starch is insoluble, amylodextrin soluble in water, is also contested; the author finding that granulose is soluble to a considerable extent in water, not only immediately after precipitation, but when it has remained for twenty-four hours under absolute alcohol. Other differences pointed out by W. Nageli, Brukner also maintains to be non-existent, and he regards amidulin and amylodextrin as identical. Brucke gave the name erythrogranulose to a substance nearly related to granulose, but with a stronger affinity for iodine, and receiving from it not a blue but a red color. Brukner regards the red color as resulting from a mixture of erythrodextrin, and the greater solubility of this substance in water. |
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