Scientific American Supplement, No. 799, April 25, 1891 by Various
page 98 of 124 (79%)
page 98 of 124 (79%)
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non-oxidizable electrodes was most efficacious after the temperature of
the fluid acted upon rose 4° or 5°; but the cost of working made it impossible on a large scale. After a long series of experiments, iron plates were used as electrodes, with remarkable results, for the compounds of iron formed not only deodorized the samples of sewage acted on, but produced complete precipitation of the matters in suspension, and also of the soluble organic matter; the resulting effluents remaining perfectly free from putrefaction. The first part of the process is well illustrated by the small experiments now shown; the organic matter in suspension and in solution separates into flocculent particles, which rise to the top of the liquid and remain until the bubbles of hydrogen which have carried them up escape, when the solid matter will precipitate. In the arrangement adopted on a working scale, the separated particles precipitate readily. As an illustration of the action upon organic matter in solution I take a small quantity of dye, mix it with water, and placing the connected iron electrodes in the mixture, the dye in solution separates into flocculent particles. The electrolytical action is of course easily understood, but the chemical changes that take place need an explanation. At the positive pole, hypochlorite of iron seems to be formed at first, but this is quickly changed into a protochloride, and as at the negative pole an alkaline reaction takes place, the iron salt is precipitated in the form of the ferrous hydrated oxide, together with the organic matters in suspension and solution. Owing to the carbonates that are always present in sewage, ferrous carbonate is also formed. The success of these laboratory experiments led me to a trial of the process on a larger scale, for hitherto only a gallon at any one time |
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