Faraday as a Discoverer by John Tyndall
page 46 of 138 (33%)
page 46 of 138 (33%)
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inquiry, which was received by the Royal Society on Nov. 30, 1833,
though not so important as those which precede and follow it, illustrates throughout his strength as an experimenter. The power of spongy platinum to cause the combination of oxygen and hydrogen had been discovered by Dobereiner in 1823, and had been applied by him in the construction of his well-known philosophic lamp. It was shown subsequently by Dulong and Thenard that even a platinum wire, when perfectly cleansed, may be raised to incandescence by its action on a jet of cold hydrogen. In his experiments on the decomposition of water, Faraday found that the positive platinum plate of the decomposing cell possessed in an extraordinary degree the power of causing oxygen and hydrogen to combine. He traced the cause of this to the perfect cleanness of the positive plate. Against it was liberated oxygen, which, with the powerful affinity of the 'nascent state,' swept away all impurity from the surface against which it was liberated. The bubbles of gas liberated on one of the platinum plates or wires of a decomposing cell are always much smaller, and they rise in much more rapid succession than those from the other. Knowing that oxygen is sixteen times heavier than hydrogen, I have more than once concluded, and, I fear, led others into the error of concluding, that the smaller and more quickly rising bubbles must belong to the lighter gas. The thing appeared so obvious that I did not give myself the trouble of looking at the battery, which would at once have told me the nature of the gas. But Faraday would never have been satisfied with a deduction if he could have reduced it to a fact. And he has taught me that the fact here is the direct reverse of what I supposed it to be. The small bubbles are oxygen, and their smallness is due to the perfect cleanness of the surface on which they are liberated. |
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