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An Introductory Course of Quantitative Chemical Analysis - With Explanatory Notes by Henry P. Talbot
page 10 of 272 (03%)
In !volumetric! analysis, instead of the final weighing of a definite
body, a well-defined reaction is caused to take place, wherein the
reagent is added from an apparatus so designed that the volume of the
solution employed to complete the reaction can be accurately measured.
The strength of this solution (and hence its value for the reaction
in question) is accurately known, and the volume employed serves,
therefore, as a measure of the substance acted upon. An example will
make clear the distinction between these two types of analysis.
The percentage of chlorine in a sample of sodium chloride may be
determined by dissolving a weighed amount of the chloride in water
and precipitating the chloride ions as silver chloride, which is
then separated by filtration, ignited, and weighed (a !gravimetric!
process); or the sodium chloride may be dissolved in water, and a
solution of silver nitrate containing an accurately known amount of
the silver salt in each cubic centimeter may be cautiously added from
a measuring device called a burette until precipitation is complete,
when the amount of chlorine may be calculated from the number of cubic
centimeters of the silver nitrate solution involved in the reaction.
This is a !volumetric! process, and is equivalent to weighing without
the use of a balance.

Volumetric methods are generally more rapid, require less apparatus,
and are frequently capable of greater accuracy than gravimetric
methods. They are particularly useful when many determinations of the
same sort are required.

In !colorimetric! analyses the substance to be determined is converted
into some compound which imparts to its solutions a distinct color,
the intensity of which must vary in direct proportion to the amount of
the compound in the solution. Such solutions are compared with respect
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