Scientific American Supplement, No. 795, March 28, 1891 by Various
page 87 of 136 (63%)
page 87 of 136 (63%)
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I pointed out that, in an atmospheric burner, it was not the oxygen of
the air introduced combining with and burning up the hydrocarbons, and so preventing the separation of incandescent carbon, which gave the non-luminous flame, but the diluting action of the nitrogen, which acted by increasing the temperature at which the hydrocarbons are broken up, and carbon liberated, a fact which was proved by observation that heating the mixture of gas and air again restored the luminosity of the flame. This experiment clearly shows that temperature is a most important factor in the illuminating value of a flame, and this is still further shown by a study of the action of the diluents present in coal gas, the non-combustible ones being far more deleterious than the combustible, as they not only dilute, but withdraw heat. Anything which will increase the temperature of the flame will also increase the illuminating power, provided, of course, that the increase in temperature is not obtained at the expense of the too rapid combustion of the hydrocarbons. As has been shown in the experiments relating to the action of diluents on flame, already quoted, oxygen, when added to coal gas, increases its illuminating value to a marked and increasing degree, until a certain percentage has been added, after which the illuminating power is rapidly decreased, until the point is reached when the mixture becomes explosive. This is due to the fact that the added oxygen increases the temperature of the flame by doing the work of the air, but without the cooling and diluting action of the nitrogen; when, however, a certain proportion is added, it begins to burn up the heavy hydrocarbons, and although the temperature goes on increasing, the light-giving power is rapidly diminished by the |
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