Scientific American Supplement, No. 821, September 26, 1891 by Various
page 42 of 161 (26%)
page 42 of 161 (26%)
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nitro-glycerine. These experiments were first conducted in England by
private parties and by the British government, when it was found that high grade gun-cotton would give excellent results if made into a colloidal solid and used alone, or in combination with certain other constituents. With a view to saving the large quantity of solvents necessary to reduce the gun-cotton, and to get a more prompt and certain ignition with a larger grain, experiments were cautiously made by the admixture of varying proportions of nitro-glycerine to the gun-cotton when dissolved, or rather along with other solvents in the process of dissolving it. It was soon found that nitro-glycerine added in quantities, even equal in weight to the gun-cotton itself, did not materially increase the rapidity of the explosion of the compound. And it was also found that high grade gun-cotton, when combined with nitro-glycerine, gave very much better results than low grade gun-cotton. I have spoken here of high and low grade gun-cotton, when in fact the word gun-cotton should be applied only to the highest nitro-compound of cellulose. The word gun cotton has always been rather loosely used. Pyroxyline would be a better word, as this applies to all grades. When cotton fiber is soaked in a large excess of a mixture of the strongest nitric and sulphuric acids, gun-cotton proper, or that of the highest grade, is produced. When weaker acids are used, lower grades of nitro-cellulose are formed. The first mentioned or highest grade gun-cotton, when thoroughly freed from its acids, has always proved to be a perfectly stable compound. The lower grades have always been found to be unstable and subject to spontaneous decomposition. Nitro-glycerine has also been erroneously |
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