Scientific American Supplement, No. 455, September 20, 1884 by Various
page 15 of 141 (10%)
page 15 of 141 (10%)
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the rapidity with which the color can be formed, and for producing it at a
less cost. It is stated in Watts' "Dictionary of Chemistry" that it is "prepared on a large scale by mixing arsenious acid with cupric acetate and water. Five parts of verdigris are made up to a thin paste, and added to a boiling solution of 4 parts or rather more of arsenious acid in 50 parts of water. The boiling must be well kept up, otherwise the precipitate assumes a yellow-green color, from the formation of copper arsenite; in that case acetic acid must be added, and the boiling continued a few minutes longer. The precipitate then becomes crystalline, and acquires the fine green color peculiar to the aceto-arsenite." I do not know from personal knowledge, but I have always understood that the copper salt employed in its manufacture in France is the acetate. This would account, in my opinion, for the larger crystalline flakes in which it is obtained in France than can be produced by the English method of manufacturing it. Cupric acetate is never employed, I believe, in England--the much cheaper copper salt, the sulphate, being always employed. In "Miller's Chemistry" it is stated it "may be obtained by _boiling_ solutions of arsenious anhydride and cupric acetate, and adding to the mixture an equal bulk of _cold_ water." Why it should be recommended to add _cold water_, I am at a loss to understand. In Drs. Roscoe and Schorlemmer's large work on "Chemistry," and in the English edition of "Wagner's Handbook of Chemical Technology," edited by Mr. Crookes, the process as described by Dr. Ehrmann in the "Ann. Pharm.," xii., 92, is given. It is thus stated in Wagner's work: "This pigment is prepared by first separately dissolving equal parts by weight of arsenious acid and neutral acetate of copper in boiling water, and next mixing these |
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