Scientific American Supplement, No. 455, September 20, 1884 by Various
page 9 of 141 (06%)
page 9 of 141 (06%)
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then with ether, and brought under a desiccator with concentrated
sulphuric acid. In order to purify the substance, it is dissolved in water and treated with bone-black. The solution is then evaporated to a sirup, and this poured into a mixture of equal parts of anhydrous alcohol and ether. In this way the new compound is obtained as a very fine, pure white powder which rapidly settles. It has much the appearance of starch. Under the microscope it is perfectly amorphous. In the air it deliquesces much more rapidly than ignited calcium chloride. Treated with dilute mineral acids or oxalic acid on the water-bath gallisin is transformed into dextrose. It does not ferment when treated in water solution with fresh yeast. The analyses led to the formula C_{12}H_{24}O_{10}. When treated under pressure with three times its weight of acetic anhydride at 130-140° it dissolves perfectly. From the solution a product was separated which on analysis gave results agreeing with the formula C_{12}H_{18}O_{10}(C_{2}H_{3}O)_{6}. The substance appears therefore to be hexacetylgallisin. Physiological experiments on lower animals and human beings demonstrated clearly that gallisin has neither directly nor indirectly any injurious effect on the health.--_Berichte der Deutschen Chemischen Gesellschaft, 17, 1000; Amer. Chem. Jour._ * * * * * THE COMBINING WEIGHTS, VOLUMES, AND SPECIFIC GRAVITIES OF ELEMENTS AND COMPOUNDS. |
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