Scientific American Supplement, No. 829, November 21, 1891 by Various
page 23 of 146 (15%)
page 23 of 146 (15%)
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sulphuric acid. Thus:
CaCO_{3} } { CaSO_{4}.H_{2}O (gypsum) H_{2}S, } yield { and 2H_{2}O, } { CH_{4}, which is marsh gas. And 2CaCO_{3}, } { 2CaSO_{4}.H_{2}O 2H_{2}S, } yield { and 2H_{2}O_{2}, } { C_{2}H_{4}, which is _ethylene._ Tables are given showing the formulæ for the homologues of ethylene and marsh gas resulting from the increase in regular gradation of the same constituents. _Formulæ Showing how Ethylene and its Homologues (C_{n}H_{2}{n}) are Produced by the Action of the Volcanic Gases H_{2}S and H_{2}O_{2} on Limestone._ Carbonate Sulphureted Peroxide of Ethylene and of lime. hydrogen. hydrogen. Gypsum. its homologues. 2CaCO3 + 2H2S + 2H2O2 yield 2(CaSO4.H2O) + C2H4 ethylene (gaseous). 3CaCO3 + 3H2S + 3H2O2 " 3(CaSO4.H2O) + C3H6 4CaCO3 + 4H2S + 4H2O2 " 4(CaSO4.H2O) + C4H8 5CaCO3 + 5H2S + 5H2O2 " 5(CaSO4.H2O) + C5H10 6CaCO3 + 6H2S + 6H2O2 " 6(CaSO4.H2O) + C6H12 Boiling |
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