Scientific American Supplement, No. 832, December 12, 1891 by Various
page 109 of 147 (74%)
page 109 of 147 (74%)
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element, a considerable amount of additional information has been
acquired concerning the chemical behavior of fluorine, and important additions and improvements have been introduced in the apparatus employed for preparing and experimenting with the gas. M. Moissan now gathers together the results of these subsequent researches--some of which have been published by him from time to time as contributions to various French scientific journals, while others have not hitherto been made known--and publishes them in a long but most interesting paper in the October number of the _Annales de Chimîe et de Physique._ Inasmuch as the experiments described are of so extraordinary a nature, owing to the intense chemical activity of fluorine, and are so important as filling a long existing vacancy in our chemical literature, readers of _Nature_ will doubtless be interested in a brief account of them. IMPROVED APPARATUS FOR PREPARING FLUORINE. In his paper of 1887, the main outlines of which were given in _Nature_ at the time (1887, vol. xxxvii., p. 179), M. Moissan showed that pure hydrofluoric acid readily dissolves the double fluoride of potassium and hydrogen, and that the liquid thus obtained is a good conductor of electricity, rendering electrolysis possible. It will be remembered that, by passing a strong current of electricity through this liquid contained in a platinum apparatus, free gaseous fluorine was obtained at the positive pole and hydrogen at the negative pole. The amount of hydrofluoric acid employed in these earlier experiments was about fifteen grms., about six grms. of hydrogen potassium fluoride, HF.KF, being added in order to render it a conductor. Since the publication of that memoir a much larger apparatus has been |
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