Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 11 of 352 (03%)
page 11 of 352 (03%)
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|OH C_{3}H_{5}|OH, |OH which is a tri-hydric alcohol, and which occurs very widely distributed as the alcoholic or basic constituent of fats, the hydrogen atoms are replaced by the NO_{2} group, to form the highly explosive compound, nitro-glycerine. If one atom only is thus displaced, the mono-nitrate is formed thus, |ONO_{2} C_{3}H_{5}|OH; |OH and if the three atoms are displaced, C_{3}H_{5}(ONO_{2})_{3}, or the tri- nitrate, is formed, which is commercial nitro-glycerine. Another class, the nitro-celluloses, are formed from cellulose, C_{6}H_{10}O_{5}, which forms the groundwork of all vegetable tissues. Cellulose has some of the properties of the alcohols, and forms ethereal salts when treated with nitric and sulphuric acids. The hexa-nitrate, or gun-cotton, has the formula, C_{12}H_{14}O_{4}(ONO_{2})_{6}; and collodion-cotton, pyroxylin, &c., form the lower nitrates, i.e., the tetra- and penta-nitrates. These last are soluble in various solvents, such as ether-alcohol and nitro-glycerine, in which the hexa-nitrate is insoluble. They all dissolve, however, in acetone and acetic ether. The solution of the soluble varieties in ether-alcohol is known as collodion, which finds many applications in the arts. The hydrocarbon |
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