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Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 25 of 352 (07%)
in the reaction, but is absolutely necessary to combine with the water
that is formed by the decomposition, and thus to keep up the strength of
the nitric acid, otherwise lower nitrates of glycerine would be formed
that are soluble in water, and which would be lost in the subsequent
process of washing to which the nitro-compound is subjected, in order to
remove the excess of acids, the retention of which in the nitro-glycerol
is very dangerous. Nitro-glycerol, which was formerly considered to be a
nitro-substitution compound of glycerol, was thought to be formed thus--

C_{3}H_{8}O_{3} + 3HNO_{3} = C{3}H_{5}(NO_{2})_{3}O_{3} + 3H_{2}O;

but more recent researches rather point to its being regarded as a nitric
ether of glycerol, or glycerine, and to its being formed thus--

C_{3}H_{8}O_{3} + 3 HNO_{3} = C{3}H_{5}(NO_{3})_{3} + 3H_{2}O.
92 227

|OH
The formula of glycerine is C_{3}H_{8}O_{8}, or C_{3}H_{5}|OH
|OH

|ONO_{2}
and that of the mono-nitrate of glycerine, C_{3}H_{5}|OH
|OH

|ONO_{2}
and of the tri-nitrate or (nitro-glycerine), C_{3}H_{5}|ONO_{2}
|ONO_{2}

that is, the three hydrogens of the semi-molecules of hydroxyl in the
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