A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 67 of 359 (18%)
page 67 of 359 (18%)
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reaction of the potash will be destroyed. This is likewise the case
with the presence of lithia, for its peculiar red color will destroy the violet of the potash. Therefore in making investigations with the silicates which contain potash, the violet color of the latter can only be discerned when they are free from soda and lithia. B. THE BLUE COLOR. (_a._) _The Chloride of Copper._--Any of the chlorides produce a blue color in the blowpipe flame, or any salt which contains chlorine will show the blue tint, as the color in this case is referable to the chlorine itself. There are, however, some chlorides which, in consequence of the peculiar reactions of their bases, will not produce the blue color, although in these cases the blue of the chlorine will be very likely to blend itself with the color produced by the base. The chloride of copper communicates an intense blue to the flame, when fused on the platinum wire. If the heat be continued until the chlorine is driven off, then the greenish hue of the oxide of copper will be discerned. (_b._) _Lead._--Metallic lead communicates to the flame a pale blue color. The oxide reacts in the same manner. The lead-salts, whose acids do not interfere with the color, impart also a fine blue to the flame, either in the platina forceps, or the crooked wire. (_c._) _Bromide of Copper._--This salt colors the flame of a bluish-green color, but when the bromine is driven off, then we have the green of the oxide of copper. |
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