Cyclopedia of Telephony & Telegraphy Vol. 1 - A General Reference Work on Telephony, etc. etc. by Robert Millikan;Samuel McMeen;George Patterson;Kempster Miller;Charles Thom
page 125 of 497 (25%)
page 125 of 497 (25%)
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plate is the _positive_ plate, because it sends forth _positive_ ions
in the electrolyte, and, therefore, itself becomes _negatively_ charged, one will have the proper basis always to determine the direction of the current flow, which is the important thing. _Polarization._ If the simple cell already described have its terminals connected by a wire for some time, it will be found that the current rapidly weakens until it ceases to be manifest. This weakening results from two causes: first, the hydrogen gas which is liberated in the action of the cell is deposited in a layer on the copper plate, thereby covering the plate and reducing the area of contact with the liquid. This increases the internal resistance of the cell, since hydrogen is a non-conductor. Second, the plate so covered becomes in effect a hydrogen electrode, and hydrogen stands high as an electro-positive element. There is, therefore, actual reduction in the electromotive force of the cell, as well as an increase in internal resistance. This phenomenon is known as polarization, and in commercial cells means must be taken to prevent such action as far as possible. The means by which polarization of cells is prevented or reduced in practice may be divided into three general classes: First--_mechanical means_. If the hydrogen bubbles be simply brushed away from the surface of the electrode the resistance and the counter polarity which they cause will be diminished. The same result may be secured if air be blown into the solution through a tube, or if the liquid be kept agitated. If the surface of the electrode be roughened or covered with points, the bubbles collect more freely at the points and are more quickly carried |
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