Cyclopedia of Telephony & Telegraphy Vol. 1 - A General Reference Work on Telephony, etc. etc. by Robert Millikan;Samuel McMeen;George Patterson;Kempster Miller;Charles Thom
page 126 of 497 (25%)
page 126 of 497 (25%)
![]() | ![]() |
|
|
away to the surface of the liquid. These means are, however,
hardly practical except in cells for laboratory use. Second--_chemical means_. If a highly oxidizing substance be added to the electrolyte, it will destroy the hydrogen bubbles by combining with them while they are in a nascent state, and this will prevent the increase in internal resistance and the opposing electromotive force. Such substances are bichromate of potash, nitric acid, and chlorine, and are largely used. Third--_electro-chemical means_. Double cells, arranged to separate the elements and liquids by means of porous partitions or by gravity, may be so arranged that solid copper is liberated instead of hydrogen at a point where the current leaves the liquid, thereby entirely obviating polarization. This method also is largely used. _Local Action._ When a simple cell stands idle, _i.e._, with its circuit open, small hydrogen bubbles may be noticed rising from the zinc electrode instead of from copper, as is the case where the circuit is closed. This is due to impurities in the zinc plate, such as particles of iron, tin, arsenic, carbon, etc. Each of these particles acts with the surrounding zinc just as might be expected of any pair of dissimilar elements opposed to each other in an electrolyte; in other words, they constitute small voltaic cells. Local currents, therefore, are generated, circulating between the two adjacent metals, and, as a result, the zinc plate and the electrolyte are needlessly wasted and the general condition of the cell is impaired. This is called _local action_. |
|


