Cyclopedia of Telephony & Telegraphy Vol. 1 - A General Reference Work on Telephony, etc. etc. by Robert Millikan;Samuel McMeen;George Patterson;Kempster Miller;Charles Thom
page 136 of 497 (27%)
page 136 of 497 (27%)
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Manganese dioxide 45 per cent Carbon or graphite, or both 45 per cent Sal ammoniac 7 per cent Zinc chloride 3 per cent Water is added to the above and a sufficient amount of mixture is taken for each cell to fill the zinc cup about seven-eighths full when the carbon is in place. The most suitable quantity of water depends upon the original dryness and fineness of material and upon the quality of the paper lining. In some forms of dry batteries, starch or other paste is added to improve the contact of the electrolyte with the zinc and promote a more even distribution of action throughout the electrolyte. Mercury, too, is often added to effect amalgamation of the zinc. As in the ordinary wet type of LeClanché cell, the purpose of the manganese is to act as a depolarizer; the carbon or graphite being added to give conductivity to the manganese and to form a large electrode surface. It is important that the sal ammoniac, which is the active agent of the cell, should be free from lumps in order to mix properly with the manganese and carbon. A small local action takes place in the dry cell, caused by the dissimilar metals necessarily employed in soldering up the zinc cup and in soldering the terminal rod of zinc to the zinc cup proper. This action, however, is slight in the better grades of cells. As a result of this, and also of the gradual drying out of the moisture within the cell, these cells gradually deteriorate even when not in use--this is |
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