Cyclopedia of Telephony & Telegraphy Vol. 1 - A General Reference Work on Telephony, etc. etc. by Robert Millikan;Samuel McMeen;George Patterson;Kempster Miller;Charles Thom
page 140 of 497 (28%)
page 140 of 497 (28%)
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In the action of the cell, when the external circuit is closed, sulphuric acid is formed which attacks the zinc to form sulphate of zinc and to liberate hydrogen, which follows its tendency to attach itself to the copper plate. But in so doing the hydrogen necessarily passes through the solution of sulphate of copper surrounding the copper plate. The hydrogen immediately combines with the SO_{4} radical, forming therewith sulphuric acid, and liberating metallic copper. This sulphuric acid, being lighter than the copper sulphate, rises to the surface of the zinc and attacks the zinc, thus forming more sulphate of zinc. The metallic copper so formed is deposited on the copper plate, thereby keeping the surface bright and clean. Since hydrogen is thus diverted from the copper plate, polarization does not ensue. The zinc sulphate being colorless, while the copper sulphate is of a dark blue color, the separating line of the two liquids is easily distinguishable. This line is called the _blue line_ and care should be taken that it does not reach the zinc and cause a deposit of copper to be placed thereon. As has been stated, these two liquids do not mix readily, but they will eventually mingle unless the action of the cell is sufficient to use up the copper sulphate as speedily as it is dissolved. Thus it will be seen that while the cell is free from polarization and local action, there is, nevertheless, a deteriorating effect if the cell is allowed to remain long on open circuit. Therefore, it should be used when a constant current is required. Prevention of Creeping:--Much trouble has been experienced in gravity |
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