Scientific American Supplement, No. 794, March 21, 1891 by Various
page 111 of 146 (76%)
page 111 of 146 (76%)
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troubles inseparable from the storage of light naphtha in bulk.
In using this oil as an enricher, it must be cracked in the presence of carbon, and it is of the greatest importance that the temperature should not be too high, as the benzene is easily broken down to simpler hydrocarbons of far lower illuminating value. This fact is very clearly brought out by a series of experiments I have made, in which the phenoloid oil was cracked by passing it through an iron tube packed with coke and heated to various temperatures, the hydrocarbons being much more easily broken up under these conditions than if mixed with diluents, such as water gas: RESULTS OBTAINED ON CRACKING PHENOLOID OIL. I. II. III. Temperature. 600° C. 800° C. 1,000° C. Volume of gas per gallon. 41.6 c.f. 76.8 c.f. 121.6 c.f. COMPOSITION OF THE GAS. Hydrogen. 34.0 36.0 37.0 Methane. 20.0 26.0 49.0 Olefines. 11.0 5.0 Nil. Ethane. 16.0 9.0 Nil. Carbon monoxide. 13.0 15.0 12.0 Carbon dioxide. 2.0 4.0 2.0 Oxygen. 2.0 1.0 Nil. Nitrogen. 2.0 4.0 Nil. |
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