Scientific American Supplement, No. 794, March 21, 1891 by Various
page 34 of 146 (23%)
page 34 of 146 (23%)
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saltpeter, fifteen per cent of charcoal, and ten per cent. of sulphur.
The most important of the high explosives are formed by the action of nitric acid upon organic substances or other hydrocarbons, the compound radical NO2 being substituted for a portion of the hydrogen in the substance. The bodies thus formed are in a condition of unstable equilibrium; but if well made from good material, they become stable in their instability, very much like Prince Rupert's drops, those little glass pellets which endure almost any amount of rough usage; but once cracked, fly into infinitesimal fragments. The power exerted by these nitro-substitution products is due to the fact that they detonate, i.e., they are instantaneously converted into colorless gas at a very high temperature, and in addition they have almost no solid residue. Nitro-glycerine actually leaves none at all, while gunpowder leaves sixty-eight per cent. The first departure in gunpowder from the old-time constituents of black powder just mentioned was for the purpose of obtaining less pressure and slower combustion than could be produced by mere granulating or caking. This was accomplished by using underburned charcoal, together with sugar and about one and one-half per cent. of water. This is the brown powder most generally used at present and with satisfactory results; but the abstraction of its moisture increases its rapidity of combustion to a dangerous degree, besides which the underburned charcoal is itself unstable. The next change demanded is smokelessness, and to accomplish it recourse is had to the high explosive field, mechanically mixing various substances with them to reduce and regulate their rapidity of action. Just now some form of gun-cotton is most in use mixed with nitrate of ammonia, camphor and other articles. The tendency of these |
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