Scientific American Supplement, No. 794, March 21, 1891 by Various
page 63 of 146 (43%)
page 63 of 146 (43%)
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for some time, finely divided material is filled in at the top. The
outer portion of the larger lumps is always overburnt, and in the upper part of the furnace the presence of shining crystalline particles generally indicates the fact that some gypsum has remained unchanged. Provided that the amount of unburnt and overburnt material does not exceed about 30 per cent. of the total, the plaster is suitable for many applications. It was early observed that set plaster could be revivified by a second baking, but attempts in this direction were not uniformly successful, it being found that the dehydrated substance in some cases refused to set with water. It behaved in fact similarly to the natural anhydrous calcium sulphate which is unaffected by water. These failures were found to be due to the employment of too high a temperature, and such plaster was termed _dead burnt_. Although this fact was ascertained long ago, yet ignorance of what had already been done has probably been the cause of many disappointments in attempts at revivification which have been made from time to time by persons unacquainted with the history of the subject. The view generally adopted with regard to the theory of these processes is that plaster consists of anhydrous calcium sulphate, CaSO4, in a condition probably amorphous, different from that of natural crystallized CaSO4, known to mineralogists under the name of anhydrite. By the influence of a high temperature it appears probable that a molecular change is gradually induced with production of a crystalline structure, and probably an increase of specific gravity, resulting in the artificial reproduction of the mineral anhydrite. No determination appears to have been published of the specific gravity of plaster prepared by complete baking at a low |
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