Scientific American Supplement, No. 794, March 21, 1891 by Various
page 68 of 146 (46%)
page 68 of 146 (46%)
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it has a greater attraction than for the other 3/4. Having a similar
bearing is the fact that when burned at lower temperatures, gypsum only loses the last portions of water with extreme slowness. Now, if it be the case that anhydrous calcium sulphate has a greater attraction for the first half molecule of water, then the operation of hydration will proceed very rapidly at first, more slowly afterward. Many such cases are known, e.g., that of copper sulphate. Conversely, if only 3/4 of the water of hydration be expelled during the baking of gypsum, the material obtained should hydrate itself more slowly. For our present purpose it will be convenient to recalculate the numbers given by Landrin (_vide supra_) so as to make the calcium sulphate and water add up to 100. This treatment of the numbers gives a mean result for the six analyses of 7.68 per cent. of water, the amounts not varying by more than 1 per cent. It will be seen that the dehydration has never passed the composition corresponding to 2 CaSO4 + H2O; indeed, the material approximates more nearly to the composition 3 CaSO4 + H2O. It appears probable, therefore, that in the successful preparation of plaster the whole, or nearly the whole, of the gypsum is changed, but that this change does not result in the production of CaSO4, or of a mixture of CaSO4 and CaSO4 + 2 H2O, but of a lower hydrate of calcium sulphate. In the case of the analyses, given by Landrin, of fine plaster for potteries, the percentages of water (8.14 and 8.08) correspond closely to that of a hydrate, 3 CaSO4 + 2 H2O, which would contain 8.1 per cent. of water. Some surprise may have been excited by the fact that the well known |
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