Scientific American Supplement, No. 441, June 14, 1884. by Various
page 12 of 155 (07%)
page 12 of 155 (07%)
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suspecting that the amount of heat developed or absorbed by chemical
reaction should be as much a property of the substances entering into combination as their atomic weights. Solid ground for this expectation lies in the dynamic theory of heat. A body of water at a given height is competent by its fall to produce a definite and invariable quantity of heat or work, and in the same way two substances falling together in chemical union acquire a definite amount of kinetic energy, which, if not expended in the work of molecular changes, may also by suitable arrangements be made to manifest a definite and invariable quantity of heat. At the end of last century Lavoisier and Laplace, and after them, down to our own time, Dulong, Desprez, Favre and Silbermann, Andrews, Berthelot, Thomson, and others, devoted much time and labor to the experimental determination of the heat of combustion and the laws which governed its development. Messrs. Favre and Silbermann, in particular, between the years 1845 and 1852, carried out a splendid series of experiments by means of the apparatus partly represented in Fig. 1 (opposite), which is a drawing one-third the natural size of the calorimeter employed. It consisted essentially of a combustion chamber formed of thin copper, gilt internally. The upper part of the chamber was fitted with a cover through which the combustible could be introduced, with a pipe for a gas jet, with a peep hole closed by adiathermanous but transparent substances, alum and glass, and with a branch leading to a thin copper coil surrounding the lower part of the chamber and descending below it. The whole of this portion of the apparatus was plunged into a thin copper vessel, silvered internally and filled with water, which was kept thoroughly mixed by means of agitators. This second vessel stood inside a third one, the sides and bottom of which were covered with the skins of swans with the down on, |
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