Scientific American Supplement, No. 421, January 26, 1884 by Various
page 17 of 118 (14%)
page 17 of 118 (14%)
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The rendering of these couples is considerable; the small cells shown in Figs. 1 and 2 give about two amperes in short circuit; the large one gives 16 to 20 amperes. Two of these elements can replace a large Bunsen cell. They are remarkably constant. We may say that with a depolarizing surface double that of the zinc the battery will work without notable polarization, and almost until completely exhausted, even under the most unfavorable conditions. The transformation of the products, the change of the alkali into an alkaline salt of zinc, does not perceptibly vary the internal resistance. This great constancy is chiefly due to the progressive reduction of the depolarizing electrode to the state of very conductive metal, which augments its conductivity and its depolarizing power. The peroxide of manganese, which forms the base of an excellent battery for giving a small rendering, possesses at first better conductivity than oxide of copper, but this property is lost by reduction and transformation into lower oxides. It follows that the copper battery will give a very large quantity of electricity working through low resistances, while under these conditions manganese batteries are rapidly polarized. The energy contained in an oxide of copper and potash battery is very great, and far superior to that stored by an accumulator of the same weight, but the rendering is much less rapid. Potash may be employed in concentrated solution at 30, 40, 60 per cent.; solid potash can dissolve the oxide of zinc furnished by a weight of zinc more than one-third of its own weight. The quantity of oxide of copper to be employed exceeds by nearly one-quarter the weight of zinc which enters into action. These data allow of the reduction of the necessary |
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