American Hand Book of the Daguerrotype by S. D. (Samuel Dwight) Humphrey
page 49 of 162 (30%)
page 49 of 162 (30%)
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Preparation.--The mother-liquor containing bromides is treated with a current of chlorine gas, which decomposes these salts, setting the bromine free, which at once colors the liquid to a reddish brown color. Ether is added and shaken with the liquid, until all the bromine is taken up by the ether, which acquires a fine red color and separates from the saline liquid. [page 74] Solution of caustic potash is then added to the ethereal solution, forming bromide of potassium and bromate of potash. This solution is evaporated to dryness, and the salts being collected are heated in a glass retort with sulphuric acid and a little oxide of manganese. The bromine is distilled, and is condensed in a cooled receiver, into a red liquid. Properties.--Bromine somewhat resembles chlorine in its odor, but is more offensive. At common temperatures it is a very volatile liquid, of a deep red color, and with a specific gravity of 3, being one of the heaviest fluids known. Sulphuric acid floats on its surface, and is used to prevent its escape. At zero it freezes into a brittle solid. A few drops in a large flask will fill the whole vessel when slightly warmed, with blood red vapors, which have a density of nearly 6.00, air being one. It is a non-conductor of electricity, and suffers no change of properties from heat, or any other of the imponderable agents. It dissolves slightly in water, forming a bleaching solution. Chloride of Bromine.--This as an accelerating agent is by many considered superior |
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