American Hand Book of the Daguerrotype by S. D. (Samuel Dwight) Humphrey
page 69 of 162 (42%)
page 69 of 162 (42%)
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Prussic acid is then generated and passes through the tube to
the recipient vessel, which is to be charged with liquor potassae. "When the potash is saturated, the operation is completed. The Germans recommend a strong, alcoholic solution of potassa to be used in the second vessel, for in this case, the hydrocyanic or prussic acid combines with the potassa, forming a hydrocyanate of potassa, or, the water being abstracted, the cyanuret of potassium, which spontaneously precipitates, on the saturation of the fluid, the cyanuret, being insoluble in strong alcohol. The ferrocyanate of potash may be considered as containing three equivalents of hydrocyanic acid, two of potash and one of iron; but, unfortunately, we can only obtain half the acid from the salt, owing to the formation of a compound during its decomposition which resists the action of the acid. The decomposition of this salt taking 2 equivalents or 426 grains (to avoid fractions) would afford 3 equivalents or 81 grains of hydrocyanic, or prussic acid, capable of forming 198 grains of cyanuret of potassium, while in the retort there would remain 384 grains or 3 equivalents of bisulphate of potash, and 1 equivalent or 174 grains of a peculiar compound, said to contain 3 equivalents of cyanogen, 1 of potassium, and one of iron (Pereira). It is manifest that, but for this later compound, we might double the quantity of hydrocyanic acid from the yellow salt." The decomposition just described is the one usually received; but too much reliance must not be placed on its accuracy, for the analysis of the several compounds is too difficult for the results to be fully admitted. The residue left in |
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