American Hand Book of the Daguerrotype by S. D. (Samuel Dwight) Humphrey
page 83 of 162 (51%)
page 83 of 162 (51%)
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Hydrate of Lime.--The operation by which water is combined with lime is called slaking. Take a piece of quick lime, common lime used in mortar, and immerse it in warm water for about fifteen seconds; then place it in an iron or tin vessel. It will soon begin to swell, evolving a great deal of heat and emitting steam, and soon falls into a fine powder, hydrate of lime. This should be well stirred and allowed to cool, and then bottled in order to prevent it from giving off the hydrate and recovering the carbonic acid from the atmosphere. The last is detrimental to its use with bromine, and is one cause of the complaint that "it will not take bromine." The hydrate of lime should, not be dried over a heat, as has been supposed by many, for in that case the hydrogen is expelled and it returns to a carbonate. It is advisable to cool it in a damp place like a ground cellar. Much of the lime in our market will not, except it be quite damp, combine with the bromine. This is owing to impurities. Nothing is equal to oyster-shell lime, which I use altogether. Bromide of Lime.--In preparing large quantities of this, we adopt the following method: Fill a four-quart bottle about two-thirds full of hydrate of lime; pour into this about one or two ounces of bromine; then shake well, add more of the bromine, shake well and let it stand for a few hours, adding sufficient bromine to give it a fine red color. It is better when kept in the large bottles, as it forms a more perfect combination: in other words it improves by age. Use.--Coat over the iodine to a rose red and then over this mixture to a purple or slate; recoat over the first about one fourth as long |
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