Scientific American Supplement, No. 443, June 28, 1884 by Various
page 66 of 107 (61%)
page 66 of 107 (61%)
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the real cause of the voltaic current. The results of them are
contained in twenty tables; and by comparing them with each other, and also by means of additional experiments, the following general conclusions and chief facts were obtained. When metals in liquids are heated, they are more frequently rendered positive than negative in the proportion of about 2.8 to 1.0; and while the proportion in weak solutions was about 2.29 to 1.0, in strong ones it was about 3.27 to 1.0, and this accords with their thermo-electric behavior as metals alone. The thermo-electric order of metals in liquids was, with nearly every solution, whether strong or weak, widely different from the thermo-electric order of the same metals alone. A conclusion previously arrived at was also confirmed, viz., that the liquids in which the hot metal was thermo-electro-positive in the largest proportion of cases were those containing highly electro-positive bases, such as the alkali metals. The thermo-electric effect of _gradually_ heating a metal in a liquid was sometimes different from that of _suddenly_ heating it, and was occasionally attended by a reversal of the current. Degree of strength of liquid greatly affected the thermo-electric order of metals. Increase of strength usually and considerably increased the potential of metals thermo-electro-negative in liquids, and somewhat increased that of those positive in liquids. The electric potential of metals, thermo-electro-positive in weak liquids, was usually about 3.87 times, and in strong ones 1.87 times, as great as of those which were negative. The potential of the strongest thermo-electric couple, viz., that of aluminum in weak solution of sodic phosphate, was 0.66 volt for 100° F. difference of |
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