Scientific American Supplement, No. 443, June 28, 1884 by Various
page 70 of 107 (65%)
page 70 of 107 (65%)
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thermo-electric actions of metals in liquids. Not only was the
relative number of cases in which the volta-negative metal was the most corroded increased by rise of temperature, but also the average relative loss by corrosion of the negative to that of the positive one was increased from 3.11 to 6.32. The explanation most consistent with all the various results and conclusions is a kinetic one: That metals and electrolytes are throughout their masses in a state of molecular vibration. That the molecules of those substances, being frictionless bodies in a frictionless medium, and their motion not being dissipated by conduction or radiation, continue incessantly in motion until some cause arises to prevent them. That each metal (or electrolyte), when unequally heated, has to a certain extent an unlike class of motions in its differently heated parts, and behaves in those parts somewhat like two metals (or electrolytes), and those unlike motions are enabled, through the intermediate conducting portion of the substance, to render those parts electro-polar. That every different metal and electrolyte has a different class of motions, and in consequence of this, they also, by contact alone with each other at the same temperature, become electro-polar. The molecular motion of each different substance also increases at a different rate by rise of temperature. This theory is equally in agreement with the chemico-electric results. In accordance with it, when in the case of a metal and an electrolyte, the two classes of motions are sufficiently unlike, chemical corrosion of the metal by the liquid takes place, and the voltaic current originated by inherent molecular motion, under the condition of contact, is maintained by the portions of motion lost by the metal and |
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