Scientific American Supplement, No. 611, September 17, 1887 by Various
page 66 of 143 (46%)
page 66 of 143 (46%)
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ammonia and sulphuric acid are resulting products, in the compound
state of sulphate of ammonia. The formation of the ammonia produced in the process is probably due to the decomposition of nitrogenous bodies contained in solution in the liquor--the sulphocyanide, for instance; the nitrogen being given off in the form of ammonia. Of the sulphuric acid produced, we look upon the sulphureted hydrogen as the source, also any sulphites existing in the liquor, which in their volatile state take up the atom of oxygen necessary for their conversion into sulphate. [Illustration] The apparatus used in working the process consists of a tower still, containing a number of superposed trays about 3 or 4 inches apart, with a lipped hole through the bottom of each at the side. The trays are so placed in the tower that the holes are at alternate sides. The liquor passes into the top of the still, and zigzags down through the series of trays, as in an ordinary Coffey still. The bottom tray differs from the rest; being much deeper, and having holes through it connecting it with the furnace, which is set immediately below it. The products of combustion of the fuel are caused to pass from the furnace up through the holes in the trays in the still, and, together with the gases evolved from the liquor, are directed into the saturator, where the sulphate of ammonia is obtained either in solution or in the crystalline state. Where the process is at present being worked, an exhauster is used to draw the furnace gases through the still; but it might be advantageous to use a blower. |
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