History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 31 of 296 (10%)
page 31 of 296 (10%)
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composition of diamonds. With the great lens of Tschirnhausen
belonging to the Academy he succeeded in burning up several diamonds, regardless of expense, which, thanks to his inheritance, he could ignore. In this process he found that a gas was given off which precipitated lime from water, and proved to be carbonic acid. Observing this, and experimenting with other substances known to give off carbonic acid in the same manner, he was evidently impressed with the now well-known fact that diamond and charcoal are chemically the same. But if he did really believe it, he was cautious in expressing his belief fully. "We should never have expected," he says, "to find any relation between charcoal and diamond, and it would be unreasonable to push this analogy too far; it only exists because both substances seem to be properly ranged in the class of combustible bodies, and because they are of all these bodies the most fixed when kept from contact with air." As we have seen, Priestley, in 1774, had discovered oxygen, or "dephlogisticated air." Four years later Lavoisier first advanced his theory that this element discovered by Priestley was the universal acidifying or oxygenating principle, which, when combined with charcoal or carbon, formed carbonic acid; when combined with sulphur, formed sulphuric (or vitriolic) acid; with nitrogen, formed nitric acid, etc., and when combined with the metals formed oxides, or calcides. Furthermore, he postulated the theory that combustion was not due to any such illusive thing as "phlogiston," since this did not exist, and it seemed to him that the phenomena of combustion heretofore attributed to phlogiston could be explained by the action of the new element oxygen and heat. This was the final blow to the phlogiston theory, which, |
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