History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 33 of 296 (11%)
page 33 of 296 (11%)
|
This new work when given to the world was not merely an
epoch-making book; it was revolutionary. It not only discarded phlogiston altogether, but set forth that metals are simple elements, not compounds of "earth" and "phlogiston." It upheld Cavendish's demonstration that water itself, like air, is a compound of oxygen with another element. In short, it was scientific chemistry, in the modern acceptance of the term. Lavoisier's observations on combustion are at once important and interesting: "Combustion," he says, ". . . is the decomposition of oxygen produced by a combustible body. The oxygen which forms the base of this gas is absorbed by and enters into combination with the burning body, while the caloric and light are set free. Every combustion necessarily supposes oxygenation; whereas, on the contrary, every oxygenation does not necessarily imply concomitant combustion; because combustion properly so called cannot take place without disengagement of caloric and light. Before combustion can take place, it is necessary that the base of oxygen gas should have greater affinity to the combustible body than it has to caloric; and this elective attraction, to use Bergman's expression, can only take place at a certain degree of temperature which is different for each combustible substance; hence the necessity of giving the first motion or beginning to every combustion by the approach of a heated body. This necessity of heating any body we mean to burn depends upon certain considerations which have not hitherto been attended to by any natural philosopher, for which reason I shall enlarge a little upon the subject in this place: "Nature is at present in a state of equilibrium, which cannot |
|