History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 38 of 296 (12%)
page 38 of 296 (12%)
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oxygen gas to form water. If it be true that this combination
consists essentially of the union of atoms one with another (each single atom of hydrogen united to a single atom of oxygen), then the relative weights of the original masses of hydrogen and of oxygen must be also the relative weights of each of their respective atoms. If one pound of hydrogen unites with five and one-half pounds of oxygen (as, according to Dalton's experiments, it did), then the weight of the oxygen atom must be five and one-half times that of the hydrogen atom. Other compounds may plainly be tested in the same way. Dalton made numerous tests before he published his theory. He found that hydrogen enters into compounds in smaller proportions than any other element known to him, and so, for convenience, determined to take the weight of the hydrogen atom as unity. The atomic weight of oxygen then becomes (as given in Dalton's first table of 1803) 5.5; that of water (hydrogen plus oxygen) being of course 6.5. The atomic weights of about a score of substances are given in Dalton's first paper, which was read before the Literary and Philosophical Society of Manchester, October 21, 1803. I wonder if Dalton himself, great and acute intellect though he had, suspected, when he read that paper, that he was inaugurating one of the most fertile movements ever entered on in the whole history of science? Be that as it may, it is certain enough that Dalton's contemporaries were at first little impressed with the novel atomic theory. Just at this time, as it chanced, a dispute was waging in the field of chemistry regarding a matter of empirical fact which must necessarily be settled before such a theory as that of Dalton could even hope for a bearing. This was the |
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