History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 47 of 296 (15%)
page 47 of 296 (15%)
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when the same fibres of cotton were made use of in successive
experiments, and washed after every process in a weak solution of nitric acid, the water in the apparatus containing them, though acted on for a great length of time with a very strong power, at last produced no effects upon nitrate of silver. "In cases when I had procured much soda, the glass at its point of contact with the wire seemed considerably corroded; and I was confirmed in my idea of referring the production of the alkali principally to this source, by finding that no fixed saline matter could be obtained by electrifying distilled water in a single agate cup from two points of platina with the Voltaic battery. "Mr. Sylvester, however, in a paper published in Mr. Nicholson's journal for last August, states that though no fixed alkali or muriatic acid appears when a single vessel is employed, yet that they are both formed when two vessels are used. And to do away with all objections with regard to vegetable substances or glass, he conducted his process in a vessel made of baked tobacco-pipe clay inserted in a crucible of platina. I have no doubt of the correctness of his results; but the conclusion appears objectionable. He conceives, that he obtained fixed alkali, because the fluid after being heated and evaporated left a matter that tinged turmeric brown, which would have happened had it been lime, a substance that exists in considerable quantities in all pipe-clay; and even allowing the presence of fixed alkali, the materials employed for the manufacture of tobacco-pipes are not at all such as to exclude the combinations of this substance. |
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