History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 51 of 296 (17%)
page 51 of 296 (17%)
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of the familiar principle that opposite electricities attract one
another. When compounds are decomposed by the battery, this mutual attraction is overcome by the stronger attraction of the poles of the battery itself. This theory of binary composition of all chemical compounds, through the union of electro-positive and electro-negative atoms or molecules, was extended by Berzelius, and made the basis of his famous system of theoretical chemistry. This theory held that all inorganic compounds, however complex their composition, are essentially composed of such binary combinations. For many years this view enjoyed almost undisputed sway. It received what seemed strong confirmation when Faraday showed the definite connection between the amount of electricity employed and the amount of decomposition produced in the so-called electrolyte. But its claims were really much too comprehensive, as subsequent discoveries proved. ORGANIC CHEMISTRY AND THE IDEA OF THE MOLECULE When Berzelius first promulgated his binary theory he was careful to restrict its unmodified application to the compounds of the inorganic world. At that time, and for a long time thereafter, it was supposed that substances of organic nature had some properties that kept them aloof from the domain of inorganic chemistry. It was little doubted that a so-called "vital force" operated here, replacing or modifying the action of ordinary "chemical affinity." It was, indeed, admitted that organic compounds are composed of familiar elements--chiefly carbon, |
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