History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 55 of 296 (18%)
page 55 of 296 (18%)
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before. Avogadro's hypothesis that there are equal numbers of
these molecules in equal volumes of gases, under fixed conditions, was revived by Gerhardt, and a little later, under the championship of Cannizzaro, was exalted to the plane of a fixed law. Thenceforth the conception of the molecule was to be as dominant a thought in chemistry as the idea of the atom had become in a previous epoch. CHEMICAL AFFINITY Of course the atom itself was in no sense displaced, but Avogadro's law soon made it plain that the atom had often usurped territory that did not really belong to it. In many cases the chemists had supposed themselves dealing with atoms as units where the true unit was the molecule. In the case of elementary gases, such as hydrogen and oxygen, for example, the law of equal numbers of molecules in equal spaces made it clear that the atoms do not exist isolated, as had been supposed. Since two volumes of hydrogen unite with one volume of oxygen to form two volumes of water vapor, the simplest mathematics show, in the light of Avogadro's law, not only that each molecule of water must contain two hydrogen atoms (a point previously in dispute), but that the original molecules of hydrogen and oxygen must have been composed in each case of two atoms---else how could one volume of oxygen supply an atom for every molecule of two volumes of water? What, then, does this imply? Why, that the elementary atom has an avidity for other atoms, a longing for companionship, an "affinity"--call it what you will--which is bound to be satisfied |
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