History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 57 of 296 (19%)
page 57 of 296 (19%)
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hydrogen or two atoms of oxygen.
Evidently, then, one atom is not always equivalent to another atom of a different kind in combining powers. A recognition of this fact by Frankland about 1852, and its further investigation by others (notably A. Kekule and A. S. Couper), led to the introduction of the word equivalent into chemical terminology in a new sense, and in particular to an understanding of the affinities or "valency" of different elements, which proved of the most fundamental importance. Thus it was shown that, of the four elements that enter most prominently into organic compounds, hydrogen can link itself with only a single bond to any other element--it has, so to speak, but a single hand with which to grasp--while oxygen has capacity for two bonds, nitrogen for three (possibly for five), and carbon for four. The words monovalent, divalent, trivalent, tretrava-lent, etc., were coined to express this most important fact, and the various elements came to be known as monads, diads, triads, etc. Just why different elements should differ thus in valency no one as yet knows; it is an empirical fact that they do. And once the nature of any element has been determined as regards its valency, a most important insight into the possible behavior of that element has been secured. Thus a consideration of the fact that hydrogen is monovalent, while oxygen is divalent, makes it plain that we must expect to find no more than three compounds of these two elements--namely, H--O--(written HO by the chemist, and called hydroxyl); H--O--H (H2O, or water), and H--O--O--H (H2O2, or hydrogen peroxide). It will be observed that in the first of these compounds the atom of oxygen stands, so to speak, with one of its hands free, eagerly reaching out, therefore, for another |
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