History of Science, a — Volume 4 by Henry Smith Williams;Edward Huntington Williams
page 59 of 296 (19%)
page 59 of 296 (19%)
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are little prone to do. It seems that they are fickle to the last
degree in their individual attachments, and are as prone to break away from bondage as they are to enter into it. Thus the oxygen atom which has just flung itself into the circuit of two hydrogen atoms, the next moment flings itself free again and seeks new companions. It is for all the world like the incessant change of partners in a rollicking dance. This incessant dissolution and reformation of molecules in a substance which as a whole remains apparently unchanged was first fully appreciated by Ste.-Claire Deville, and by him named dissociation. It is a process which goes on much more actively in some compounds than in others, and very much more actively under some physical conditions (such as increase of temperature) than under others. But apparently no substances at ordinary temperatures, and no temperature above the absolute zero, are absolutely free from its disturbing influence. Hence it is that molecules having all the valency of their atoms fully satisfied do not lose their chemical activity--since each atom is momentarily free in the exchange of partners, and may seize upon different atoms from its former partners, if those it prefers are at hand. While, however, an appreciation of this ceaseless activity of the atom is essential to a proper understanding of its chemical efficiency, yet from another point of view the "saturated" molecule--that is, the molecule whose atoms have their valency all satisfied--may be thought of as a relatively fixed or stable organism. Even though it may presently be torn down, it is for the time being a completed structure; and a consideration of the valency of its atoms gives the best clew that has hitherto been obtainable as to the character of its architecture. How |
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