Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 115 of 299 (38%)
page 115 of 299 (38%)
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the advance of the artificial silk industry will be rapid enough to
relieve us of the necessity of boiling thousands of baby worms in their cradles whenever we want silk stockings. On a plain rush hurdle a silkworm lay When a proud young princess came that way. The haughty daughter of a lordly king Threw a sidelong glance at the humble thing, Little thinking she walked in pride In the winding sheet where the silkworm died. But so far we have not reached a stage where we can altogether dispense with the services of the silkworm. The viscose threads made by the process look as well as silk, but they are not so strong, especially when wet. Besides the viscose method there are several other methods of getting cellulose into solution so that artificial fibers may be made from it. A strong solution of zinc chloride will serve and this process used to be employed for making the threads to be charred into carbon filaments for incandescent bulbs. Cellulose is also soluble in an ammoniacal solution of copper hydroxide. The liquid thus formed is squirted through a fine nozzle into a precipitating solution of caustic soda and glucose, which brings back the cellulose to its original form. In the chapter on explosives I explained how cellulose treated with nitric acid in the presence of sulfuric acid was nitrated. The cellulose molecule having three hydroxyl (--OH) groups, can take up one, two or three nitrate groups (--ONO_{2}). The higher nitrates are known as guncotton and form the basis of modern dynamite and smokeless powder. |
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