Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 129 of 299 (43%)
page 129 of 299 (43%)
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simplest imaginable way. Tissue paper, that is, cellulose, is treated
with nitric acid in the presence of sulfuric acid. The nitration is not carried so far as to produce the guncotton used in explosives but only far enough to make a soluble nitrocellulose or pyroxylin. This is pulped and mixed with half the quantity of camphor, pressed into cakes and dried. If this mixture is put into steam-heated molds and subjected to hydraulic pressure it takes any desired form. The process remains essentially the same as was worked out by the Hyatt brothers in the factory they set up in Newark in 1872 and some of their original machines are still in use. But this protean plastic takes innumerable forms and almost as many names. Each factory has its own secrets and lays claim to peculiar merits. The fundamental product itself is not patented, so trade names are copyrighted to protect the product. I have already mentioned three, "parkesine," "xylonite" and "celluloid," and I may add, without exhausting the list of species belonging to this genus, "viscoloid," "lithoxyl," "fiberloid," "coraline," "eburite," "pulveroid," "ivorine," "pergamoid," "duroid," "ivortus," "crystalloid," "transparene," "litnoid," "petroid," "pasbosene," "cellonite" and "pyralin." Celluloid can be given any color or colors by mixing in aniline dyes or metallic pigments. The color may be confined to the surface or to the interior or pervade the whole. If the nitrated tissue paper is bleached the celluloid is transparent or colorless. In that case it is necessary to add an antacid such as urea to prevent its getting yellow or opaque. To make it opaque and less inflammable oxides or chlorides of zinc, aluminum, magnesium, etc., are mixed in. Without going into the question of their variations and relative merits we may consider the advantages of the pyroxylin plastics in general. |
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