Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 141 of 299 (47%)
page 141 of 299 (47%)
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analysis is easier than synthesis and that creative chemistry is the
highest branch of his art. This explains why chemists discovered how to take rubber apart over sixty years before they could find out how to put it together. The first is easy. Just put some raw rubber into a retort and heat it. If you can stand the odor you will observe the caoutchouc decomposing and a benzine-like liquid distilling over. This is called "isoprene." Any Freshman chemist could write the reaction for this operation. It is simply C_{10}H_{16} --> 2C_{5}H_{8} caoutchouc isoprene That is, one molecule of the gum splits up into two molecules of the liquid. It is just as easy to write the reaction in the reverse directions, as 2 isoprene--> 1 caoutchouc, but nobody could make it go in that direction. Yet it could be done. It had been done. But the man who did it did not know how he did it and could not do it again. Professor Tilden in May, 1892, read a paper before the Birmingham Philosophical Society in which he said: I was surprised a few weeks ago at finding the contents of the bottles containing isoprene from turpentine entirely changed in appearance. In place of a limpid, colorless liquid the bottles contained a dense syrup in which were floating several large masses of a yellowish color. Upon examination this turned out to be India rubber. But neither Professor Tilden nor any one else could repeat this |
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