Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 143 of 299 (47%)
page 143 of 299 (47%)
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the volatile colorless liquid he had put into it.
Twenty years before the discovery would have been useless, for sodium was then a rare and costly metal, a little of it in a sealed glass tube being passed around the chemistry class once a year as a curiosity, or a tiny bit cut off and dropped in water to see what a fuss it made. But nowadays metallic sodium is cheaply produced by the aid of electricity. The difficulty lay rather in the cost of the raw material, isoprene. In industrial chemistry it is not sufficient that a thing can be made; it must be made to pay. Isoprene could be obtained from turpentine, but this was too expensive and limited in supply. It would merely mean the destruction of pine forests instead of rubber forests. Starch was finally decided upon as the best material, since this can be obtained for about a cent a pound from potatoes, corn and many other sources. Here, however, the chemist came to the end of his rope and had to call the bacteriologist to his aid. The splitting of the starch molecule is too big a job for man; only the lower organisms, the yeast plant, for example, know enough to do that. Owing perhaps to the _entente cordiale_ a French biologist was called into the combination, Professor Fernbach, of the Pasteur Institute, and after eighteen months' hard work he discovered a process of fermentation by which a large amount of fusel oil can be obtained from any starchy stuff. Hitherto the aim in fermentation and distillation had been to obtain as small a proportion of fusel as possible, for fusel oil is a mixture of the heavier alcohols, all of them more poisonous and malodorous than common alcohol. But here, as has often happened in the history of industrial chemistry, the by-product turned out to be more valuable than the product. From fusel oil by the use of chlorine isoprene can be prepared, so the chain was complete. |
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