Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 145 of 299 (48%)
page 145 of 299 (48%)
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I have dropped the 16 H's or hydrogen atoms of the formula for simplicity's sake. They simply hook on wherever they can. You will see that the isoprene consists of a chain of four carbon atoms (represented by the C's) with an extra carbon on the side. In the transformation of this colorless liquid into soft rubber two of the double linkages break and so permit the two chains of 4 C's to unite to form one ring of eight. If you have ever played ring-around-a-rosy you will get the idea. In Chapter IV I explained that the anilin dyes are built up upon the benzene ring of six carbon atoms. The rubber ring consists of eight at least and probably more. Any substance containing that peculiar carbon chain with two double links C=C-C=C can double up--polymerize, the chemist calls it--into a rubber-like substance. So we may have many kinds of rubber, some of which may prove to be more useful than that which happens to be found in nature. With the structural formula of Harries as a clue chemists all over the world plunged into the problem with renewed hope. The famous Bayer dye works at Elberfeld took it up and there in August, 1909, Dr. Fritz Hofmann worked out a process for the converting of pure isoprene into rubber by heat. Then in 1910 Harries happened upon the same sodium reaction as Matthews, but when he came to get it patented he found that the Englishman had beaten him to the patent office by a few weeks. This Anglo-German rivalry came to a dramatic climax in 1912 at the great hall of the College of the City of New York when Dr. Carl Duisberg, of the Elberfeld factory, delivered an address on the latest achievements of the chemical industry before the Eighth--and the last for a long time--International Congress of Applied Chemistry. Duisberg insisted upon talking in German, although more of his auditors would have |
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