Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 148 of 299 (49%)
page 148 of 299 (49%)
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inorganic synthesis that dispenses with the aid of vegetation and starts
with coal and lime. These heated together in the electric furnace form calcium carbide and this, as every automobilist knows, gives acetylene by contact with water. From this gas isoprene can be made and the isoprene converted into rubber by sodium, or acid or alkali or simple heating. Acetone, which is also made from acetylene, can be converted directly into rubber by fuming sulfuric acid. This seems to have been the process chiefly used by the Germans during the war. Several carbide factories were devoted to it. But the intermediate and by-products of the process, such as alcohol, acetic acid and acetone, were in as much demand for war purposes as rubber. The Germans made some rubber from pitch imported from Sweden. They also found a useful substitute in aluminum naphthenate made from Baku petroleum, for it is elastic and plastic and can be vulcanized. So although rubber can be made in many different ways it is not profitable to make it in any of them. We have to rely still upon the natural product, but we can greatly improve upon the way nature produces it. When the call came for more rubber for the electrical and automobile industries the first attempt to increase the supply was to put pressure upon the natives to bring in more of the latex. As a consequence the trees were bled to death and sometimes also the natives. The Belgian atrocities in the Congo shocked the civilized world and at Putumayo on the upper Amazon the same cause produced the same horrible effects. But no matter what cruelty was practiced the tropical forests could not be made to yield a sufficient increase, so the cultivation of the rubber was begun by far-sighted men in Dutch Java, Sumatra and Borneo and in British Malaya and Ceylon. Brazil, feeling secure in the possession of a natural monopoly, made no |
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