Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 27 of 299 (09%)
page 27 of 299 (09%)
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released. During the war the American Government placed orders for
68,000,000 such grenades as are here shown.] [Illustration: © International Film Service, Inc. WOMEN IN A MUNITION PLANT ENGAGED IN THE MANUFACTURE OF TRI-NITRO-TOLUOL, THE MOST IMPORTANT OF MODERN HIGH EXPLOSIVES] The active agent in all these explosives is the nitrogen atom in combination with two oxygen atoms, which the chemist calls the "nitro group" and which he represents by NO_{2}. This group was, as I have said, originally used in the form of saltpeter or potassium nitrate, but since the chemist did not want the potassium part of it--for it fouled his guns--he took the nitro group out of the nitrate by means of sulfuric acid and by the same means hooked it on to some compound of carbon and hydrogen that would burn without leaving any residue, and give nothing but gases. One of the simplest of these hydrocarbon derivatives is glycerin, the same as you use for sunburn. This mixed with nitric and sulfuric acids gives nitroglycerin, an easy thing to make, though I should not advise anybody to try making it unless he has his life insured. But nitroglycerin is uncertain stuff to keep and being a liquid is awkward to handle. So it was mixed with sawdust or porous earth or something else that would soak it up. This molded into sticks is our ordinary dynamite. If instead of glycerin we take cellulose in the form of wood pulp or cotton and treat this with nitric acid in the presence of sulfuric we get nitrocellulose or guncotton, which is the chief ingredient of smokeless powder. |
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