Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 82 of 299 (27%)
page 82 of 299 (27%)
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eighty-four. He worked on the problem of the constitution of indigo for
fifteen years and discovered several ways of making it. It is possible to start from benzene, toluene or naphthalene. The first process was the easiest, but if you will refer to the products of the distillation of tar you will find that the amount of toluene produced is less than the naphthalene, which is hard to dispose of. That is, if a dye factory had worked out a process for making indigo from toluene it would not be practicable because there was not enough toluene produced to supply the demand for indigo. So the more complicated napthalene process was chosen in preference to the others in order to utilize this by-product. The Badische Anilin-und-Soda Fabrik spent $5,000,000 and seventeen years in chemical research before they could make indigo, but they gained a monopoly (or, to be exact, ninety-six per cent.) of the world's production. A hundred years ago indigo cost as much as $4 a pound. In 1914 we were paying fifteen cents a pound for it. Even the pauper labor of India could not compete with the German chemists at that price. At the beginning of the present century Germany was paying more than $3,000,000 a year for indigo. Fourteen years later Germany was _selling_ indigo to the amount of $12,600,000. Besides its cheapness, artificial indigo is preferable because it is of uniform quality and greater purity. Vegetable indigo contains from forty to eighty per cent. of impurities, among them various other tinctorial substances. Artificial indigo is made pure and of any desired strength, so the dyers can depend on it. The value of the aniline colors lies in their infinite variety. Some are fast, some will fade, some will stand wear and weather as long as the fabric, some will wash out on the spot. Dyes can be made that will attach themselves to wool, to silk or to cotton, and give it any shade |
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