The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
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page 10 of 178 (05%)
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semi-transparent, the beautiful pearly lustre being due to the
smoothness of the outer layer and its reflection of the light. In the silk fibre there are two distinct parts: first, the central portion, or, as we may regard it, the true fibre, chemically termed _fibroïn_; and secondly, an envelope composed of a substance or substances, chemically termed _sericin_, and often "silk-glue" or "silk-gum." Both the latter and _fibroïn_ are composed of carbon, hydrogen, nitrogen, and oxygen. Here there is thus one element more than in the vegetable fibres previously referred to, namely, nitrogen; and this nitrogen is contained in all the animal fibres. The outer envelope of silk-glue or sericin can be dissolved off the inner fibroïn fibre by means of hot water, or warm water with a little soap. Warm dilute (that is, weak) acids, such as sulphuric acid, etc., also dissolve this silk-glue, and can be used like soap solutions for ungumming silk. Dilute nitric acid only slightly attacks silk, and colours it yellow; it would not so colour vegetable fibres, and this forms a good test to distinguish silk from a vegetable fibre. Cold strong acetic acid, so-called glacial acetic acid, removes the yellowish colouring matter from raw silk without dissolving the sericin or silk-gum. By heating under pressure with acetic acid, however, silk is completely dissolved. Silk is also dissolved by strong sulphuric acid, forming a brown thick liquid. If we add water to this thick liquid, a clear solution is obtained, and then on adding tannic acid the fibroïn is precipitated. Strong caustic potash or soda dissolves silk; more easily if warm. Dilute caustic alkalis, if sufficiently dilute, will dissolve off the sericin and leave the inner fibre of fibroïn; but they are not so good for ungumming silk as soap solutions are, as the fibre after treatment with them is deficient in whiteness and brilliancy. Silk dissolves completely in hot basic zinc chloride solution, and also in an alkaline solution of copper and glycerin, which solutions do not dissolve vegetable fibres or wool. |
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