The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 34 of 178 (19%)
page 34 of 178 (19%)
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_e.g._, as boiling water under a high pressure of steam, you raise the
boiling-point. There are some industrial operations in which the action of certain boiling solutions is unavailing to effect certain decompositions or other ends when the boiling is carried on under the ordinary atmospheric pressure, and boiling in closed and strong vessels under pressure must be resorted to. Take as an example the wood-pulp process for making paper from wood shavings. Boiling in open pans with caustic soda lye is insufficient to reduce the wood to pulp, and so boiling in strong vessels under pressure is adopted. The temperature of the solution rises far above 212° F. (100° C.). Let us see what may result chemically from the attainment of such high temperatures of water in our steam boilers working under high pressures. If you blow ordinary steam at 212° F. or 100° C., into fats or oils, the fats and oils remain undecomposed; but suppose you let fatty and oily matters of animal or vegetable origin, such as lubricants, get into your boiler feed-water and so into your boiler, what will happen? I have only to tell you that a process is patented for decomposing fats with superheated steam, to drive or distil over the admixed fatty acids and glycerin, in order to show you that in your boilers such greasy matters will be more or less decomposed. Fats are neutral as fats, and will not injure the iron of the boilers; but once decompose them and they are split up into an acid called a fat acid, and glycerin. That fat acid at the high temperature soon attacks your boilers and pipes, and eats away the iron. That is one of the curious results that may follow at such high temperatures. Mineral or hydrocarbon oils do not contain these fat acids, and so cannot possibly, even with high-pressure steam, corrode the boiler metal. _Effect of Dissolved Salts on the Boiling of Water._--Let us inquire what this effect is? Suppose we dissolve a quantity of a salt in water, |
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