The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 39 of 178 (21%)
page 39 of 178 (21%)
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as regards solubility or insolubility, of the substances composing the
strata or layers of earth upon which it falls, and through which it sinks. If it meets with insoluble rocks--for all rocks are not insoluble--it remains, of course, pure and soft, and in proportion as the constituents of rock and soil are soluble, in that proportion does the water become hard. We all know how dangerous acid is in water, causing that water to act on many substances, the iron of iron vessels, the lime in soil or rock, etc., bringing iron and lime respectively into solution. Now the atmosphere contains carbonic acid, and carbonic acid occurs in the earth, being evolved by decomposing vegetation, etc. Carbonic acid is also soluble to a certain, though not large extent, in water. As we shall see, water charged with carbonic acid attacks certain substances insoluble in pure water, and brings them into solution, and thus the water soon becomes hard. About the close of the last lecture, I said that lime is, to a certain extent, soluble in cold water. The solution is called lime-water; it might be called a solution of caustic lime. When carbonic acid gas first comes in contact with such a solution, chalk or carbonate of lime, which is insoluble in water, is formed, and the lime is thus precipitated as carbonate. Supposing, however, we continued to pass carbonic acid gas into that water, rendered milky with chalk powder, very soon the liquid would clear, and we should get once more a solution of lime, but not caustic lime as it was at first, simply now a solution of carbonate of lime in carbonic acid, or a solution of bicarbonate of lime. I will take some lime-water, and I will blow through; my breath contains carbonic acid, and you will see the clear liquid become milky owing to separation of insoluble carbonate of lime, or chalk. I now continue blowing, and at length that chalk dissolves with the excess of carbonic acid, forming bicarbonate of lime. This experiment explains how it is that water percolating through or running over limestone strata dissolves out the insoluble chalk. Such |
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